Organohalogenated flame retardants and organophosphate esters in office air and dust from Sweden.

Tao, F.; Sellström, U.; de Wit, C.A.
2019 | Environ. Sci. Technol. | 53 (2124-2133)

Biodegradation of Chemicals in Unspiked Surface Waters Downstream of Wastewater Treatment Plants

2019 | Environ. Sci. Technol. | 53 (4) (1884-1892)

Development of new epoxy resin monomers – A delicate balance between skin allergy and polymerization properties

Ponting D.J., Ortega M.A., Niklasson I.B., Karlsson I., Seifert T., Steen J., Luthman K., and Karlberg A.T
2019 | Chem. Res. Toxicol. | 32 (1) (57-66)

Highly fluorinated chemicals in functional textiles can be replaced by re-evaluating liquid repellency and end-user requirements

Schellenberger, S.; Hill, P.J.; Levenstam, O.; Gillgard P.; Cousins, I.T.; Taylor, M.; Blackburn, R.S.
2019 | J. Clean. Prod. | 217 (134-143)

Improving structure and transparency in reliability evaluations of data under REACH: suggestions for a systematic method

Ellen Ingre-Khans; Marlene Ågerstrand; Christina Rudén; Anna Beronius;
2019 | Hum. Ecol. Risk Assess.

The goal of identifying hazardous chemicals registered under the Registration, Evaluation, Authorization and restriction of CHemicals (REACH) Regulation and taking appropriate risk management measures relies on robust data registrations. However, the current procedures for European chemical manufacturers and importers to evaluate data under REACH neither support systematic evaluations of data nor transparently communicate these assessments. The aim of this study was to explore how using a data evaluation method with predefined criteria for reliability and establishing principles for assigning reliability categories could contribute to more structured and transparent evaluations under REACH. In total, 20 peer-reviewed studies for 15 substances registered under REACH were selected for an in-depth evaluation of reliability with the SciRAP tool. The results show that using a method for study evaluation, with clear criteria for assessing reliability and assigning studies to reliability categories, contributes to more structured and transparent reliability evaluations. Consequently, it is recommended to implement a method for evaluating data under REACH with predefined criteria and fields for documenting and justifying the assessments to increase consistency of data evaluations and transparency.

Occurrence of legacy and alternative plasticizers in indoor dust from various EU countries and implications for human exposure via dust ingestion and dermal exposure.

Christia, C.; Poma, G.; Harrad, S.; de Wit, C.A.; Sjostrom, Y.; Leonards, P.; Lamoree, M.; Covaci, A.
2019 | Environ. Res. | 171 (204-212)

Toxicity studies used in REACH ‐ How accurately are they reported?

Ellen Ingre‐Khans; Marlene Ågerstrand; Anna Beronius; Christina Rudén;
2019 | Toxicol. Res.

Toxicity studies on chemicals registered under REACH are provided as summaries instead of submitting a full study report. Since the registration data are used by regulatory agencies to identify chemicals of concern, the study summaries must accurately reflect the information in studies. A “study summary” should include sufficient information on the objectives, methods, results and conclusions in the full study report to determine the relevance of the study. Sometimes a “robust study summary” is required, which should contain more detailed information to enable an independent assessment of the study. The aim of this investigation is to examine how well published toxicity papers were reflected in study summaries submitted by registrants under REACH. Summaries of 20 published studies (peer‐reviewed studies including one abstract) were examined and broad categories of various types of observed differences were derived. As seen, the extent to which information in the published studies was reported in the study summaries varied. It also varied how accurately the information was reflected. Differences between the published studies and the summaries included simple typing errors, unclear and incomplete reporting as well as the omission of information on for example study design, results or interpretation of the results, which in some of the cases could be considered relevant for the risk assessment. This raises concerns regarding the accuracy of study summaries and their use for decision‐making. Moreover, the possibility for third parties to independently assess and scrutinise the summaries is limited. Considering that we rely on REACH registration data for chemical safety, all data used for risk assessment should be accessible for thorough examination and fully independent assessment.

Toward a Comprehensive Global Emission Inventory of C4–C10 Perfluoroalkanesulfonic Acids (PFSAs) and Related Precursors: Focus on the Life Cycle of C6- and C10-based Products

Boucher, J.M.; Cousins, I.T.; Scheringer, M.; Hungerbuehler, K.; Wang, Z.
2019 | Environ. Sci. Technol. Lett. | 6 (1) (1-7)

Acknowledgement.

2019 | Emerging Contaminants | 5 (35-35)

Trends in MODIS and AERONET derived aerosol optical thickness over Northern Europe.

Glantz, P.; Freud, E.; Johansson, C.; Noone, K. J.; Tesche, M.
2019 | Tellus B Chem Phys Meteorol | 71 (1) (1-21)

Long-term Aqua and Terra MODIS (MODerate resolution Imaging Spectroradiometer) Collections 5.1 and 6.1 (c051 and c061, respectively) aerosol data have been combined with AERONET (AERosol RObotic NETwork) ground-based sun photometer observations to examine trends in aerosol optical thickness (AOT, at 550 nm) over Northern Europe for the months April to September. For the 1927 and 1559 daily coincident measurements that were obtained for c051 and c061, respectively, MODIS AOT varied by 86 and 90%, respectively, within the predicted uncertainty of one standard deviation of the retrieval over land (ΔAOT = ±0.05 ± 0.15·AOT). For the coastal AERONET site Gustav Dalen Tower (GDT), Sweden, larger deviations were found for MODIS c051 and c061 (79% and 75%, respectively, within predicted uncertainty). The Baltic Sea provides substantially better statistical representation of AOT than the surrounding land areas and therefore favours the investigations of trends in AOT over the region. Negative trends of 1.5% and 1.2% per year in AOT, based on daily averaging, were found for the southwestern Baltic Sea from MODIS c051 and c061, respectively. This is in line with a decrease of 1.2% per year in AOT at the AERONET station Hamburg. For the western Gotland Basin area, Sweden, negative trends of 1.5%, 1.1% and 1.6% per year in AOT have been found for MODIS c051, MODIS c061 and AERONET GDT, respectively. The strongest trend of –1.8% per year in AOT was found for AERONET Belsk, Poland, which can be compared to –1.5% per day obtained from MODIS c051 over central Poland. The trends in MODIS and AERONET AOT are nearly all statistically significant at the 95% confidence level. The strongest aerosol sources are suggested to be located southwest, south and southeast of the investigation area, although the highest prevalence of pollution events is associated with air mass transport from southwest.

Remobilization of old permafrost carbon to Chukchi Sea sediments during the end of the last deglaciation

Jannik Martens; Birgit Wild; Christof Pearce; Tommaso Tesi; August Andersson; Lisa Bröder; Matt O'Regan; Martin Jakobsson; Martin Sköld; Laura Gemery; Thomas M. Cronin; Igor Semiletov; Oleg V. Dudarev; Örjan Gustafsson
2019 | Global Biogeochem Cycles | 33

Climate warming is expected to destabilize permafrost carbon (PF‐C) by thaw‐erosion and deepening of the seasonally thawed active layer and thereby promote PF‐C mineralization to CO2 and CH4. A similar PF‐C remobilization might have contributed to the increase in atmospheric CO2 during deglacial warming after the last glacial maximum. Using carbon isotopes and terrestrial biomarkers (Δ14C, δ13C, and lignin phenols), this study quantifies deposition of terrestrial carbon originating from permafrost in sediments from the Chukchi Sea (core SWERUS‐L2‐4‐PC1). The sediment core reconstructs remobilization of permafrost carbon during the late Allerød warm period starting at 13,000 cal years before present (BP), the Younger Dryas, and the early Holocene warming until 11,000 cal years BP and compares this period with the late Holocene, from 3,650 years BP until present. Dual‐carbon‐isotope‐based source apportionment demonstrates that Ice Complex Deposit—ice‐ and carbon‐rich permafrost from the late Pleistocene (also referred to as Yedoma)—was the dominant source of organic carbon (66 ± 8%; mean ± standard deviation) to sediments during the end of the deglaciation, with fluxes more than twice as high (8.0 ± 4.6 g·m−2·year−1) as in the late Holocene (3.1 ± 1.0 g·m−2·year−1). These results are consistent with late deglacial PF‐C remobilization observed in a Laptev Sea record, yet in contrast with PF‐C sources, which at that location were dominated by active layer material from the Lena River watershed. Release of dormant PF‐C from erosion of coastal permafrost during the end of the last deglaciation indicates vulnerability of Ice Complex Deposit in response to future warming and sea level changes.

A Multi-Pollutant Air Quality Health Index (AQHI) Based on Short-Term Respiratory Effects in Stockholm, Sweden

Olstrup, H.; Johansson, C.; Forsberg, B.; Tornevi, A.; Ekebom, A.; Meister, K.
2019 | Int J Environ Res Public Health | 16 (1) (105-129)

In this study, an Air Quality Health Index (AQHI) for Stockholm is introduced as a tool to capture the combined effects associated with multi-pollutant exposure. Public information regarding the expected health risks associated with current or forecasted concentrations of pollutants and pollen can be very useful for sensitive persons when planning their outdoor activities. For interventions, it can also be important to know the contribution from pollen and the specific air pollutants, judged to cause the risk. The AQHI is based on an epidemiological analysis of asthma emergency department visits (AEDV) and urban background concentrations of NOx, O3, PM10 and birch pollen in Stockholm during 2001–2005. This analysis showed per 10 µg·m–3 increase in the mean of same day and yesterday an increase in AEDV of 0.5% (95% CI: −1.2–2.2), 0.3% (95% CI: −1.4–2.0) and 2.5% (95% CI: 0.3–4.8) for NOx, O3 and PM10, respectively. For birch pollen, the AEDV increased with 0.26% (95% CI: 0.18–0.34) for 10 pollen grains·m–3. In comparison with the coefficients in a meta-analysis, the mean values of the coefficients obtained in Stockholm are smaller. The mean value of the risk increase associated with PM10 is somewhat smaller than the mean value of the meta-coefficient, while for O3, it is less than one fifth of the meta-coefficient. We have not found any meta-coefficient using NOx as an indicator of AEDV, but compared to the mean value associated with NO2, our value of NOx is less than half as large. The AQHI is expressed as the predicted percentage increase in AEDV without any threshold level. When comparing the relative contribution of each pollutant to the total AQHI, based on monthly averages concentrations during the period 2015–2017, there is a tangible pattern. The AQHI increase associated with NOx exhibits a relatively even distribution throughout the year, but with a clear decrease during the summer months due to less traffic. O3 contributes to an increase in AQHI during the spring. For PM10, there is a significant increase during early spring associated with increased suspension of road dust. For birch pollen, there is a remarkable peak during the late spring and early summer during the flowering period. Based on monthly averages, the total AQHI during 2015–2017 varies between 4 and 9%, but with a peak value of almost 16% during the birch pollen season in the spring 2016. Based on daily mean values, the most important risk contribution during the study period is from PM10 with 3.1%, followed by O3 with 2.0%.

Contact information

Visiting addresses:

Geovetenskapens Hus,
Svante Arrhenius väg 8, Stockholm

Arrheniuslaboratoriet, Svante Arrhenius väg 16, Stockholm (Unit for Toxicological Chemistry)

Mailing address:
Department of Environmental Science
Stockholm University
106 91 Stockholm

Press enquiries should be directed to:

Stella Papadopoulou
Science Communicator
Phone +46 (0)8 674 70 11
stella.papadopoulou@aces.su.se